Publications

  1.  S. Caffieri, G. Miolo, R. Seraglia, D. Dalzoppo, F. M. Toma, G. M. J. Beijersbergen van Henegouwen, “Photoaddion of fluphenazine to nucleophiles in peptides and proteins. Possible cause of immune side effects”, Chem. Res. Toxicol 2007, 20 (10), pp 1470-1476 [DOI]

  2. A. Garcia, M. A. Herrero, S. Frein, R. Deschenaux, R. Munoz, I. Bustero, F. M. Toma, M. Prato, “Synthesis of dendrimer-carbon nanotubes conjugates” Phys. Stat. Sol. (a) 2008, 205 (6), pp 1402-1407 [DOI]

  3. C. Gaillard, G. Cellot, Li Shouping, F. M. Toma, H. Dumortier, G. Spalluto, B. Cacciari and M. Prato, “Carbon nanotubes carrying cell-adhesion peptides do not interfere with neuronal functionality”, Adv. Mater. 2009, 21 (28), pp 2903-2908 [DOI]

  4. M. A. Herrero, F. M. Toma, K. T. Al-Jamal, K. Kostarelos, A. Bianco, T. Da Ros, F. Bano, L. Casalis, G. Scoles, M. Prato, “Synthesis and characterization of a carbon nanotube-dendron series for efficient siRNA delivery”, J. Am. Chem. Soc. 2009, 131 (28), pp 9843-9848 [DOI]

  5. P. Singh, J. Kumar, F. M. Toma, Raya J., Prato M., Fabre B., Verma S., Bianco A., “Synthesis and characterization of nucleobase-carbon nanotube hybrids”, J. Am. Chem. Soc. 2009, 131 (37), pp 13555-13562 [DOI]

  6. I. Guryanov, F. M. Toma, A. Montellano López, M. Carraro, T. Da Ros, G. Angelini, E. D’Aurizio, A. Fontana, M. Maggini, M. Prato, M. Bonchio, “Microwave-assisted functionalization of carbon nanostructures in ionic liquids”, Chem-Eur. J. 2009, 15(46), pp 12837-12845 [DOI]

  7. C. Samorì, H. Ali-Boucetta, R. Sainz, C. Guo, F. M. Toma, C. Fabbro, T. Da Ros, M. Prato, K. Kostarelos, A. Bianco, “Enhanced anticancer activity of multi-walled carbon nanotube-methotrexate conjugates using cleavable linkers”, Chem. Commun. 2010, 46 (9), pp 1494-1496 [DOI]

  8. C. Samorì, R. Sainz, C. Ménard-Moyon, F. M. Toma, E. Venturelli, P. Singh, M. Ballestri, M. Prato, A. Bianco, “Potentiometric titration as a straightforward method to assess the amount of functional groups on shortened carbon nanotubes”, Carbon 2010, 48 (9), pp 2447-2454) [DOI]

  9. K. T. Al-Jamal, F. M. Toma, A. Yilmazer, H. Ali-Boucetta, A. Nunes, M. A. Herrero, B. Tian, A. Eddaoui, A. Bianco, M. Prato, K. Kostarelos, “Enhanced cellular internalization and gene silencing with a series of cationic dendron-multiwalled carbon nanotube:siRNA complexes”, FASEB J. 2010, 24 (11), pp 4354-4365 [DOI]

  10. F. M. Toma, A. Sartorel, M. Iurlo, M. Carraro, P. Parisse, C. Maccato, S. Rapino, B. Rodriguez Gonzalez, H. Amenitsch, T. Da Ros, L. Casalis, A. Goldoni, M. Marcaccio, G. Scorrano, G. Scoles, F. Paolucci, M. Prato, M. Bonchio, “Efficient water oxidation at carbon nanotube/polyoxometalate electrocatalytic interfaces", Nat. Chem. 2010, 2, 826-831. Highlighted by Nat. Chem., 2010, 2, 804-805 [DOI]

  11. A. Sartorel, M. Truccolo, S. Berardi, M. Gardan, M. Carraro, F. M. Toma, G. Scorrano, M. Prato, M. Bonchio, “Oxygenic polyoxometalates: a new class of molecular propellers”, Chem. Comm. 2011, 47 (6), pp 1716-1718. Highlighted by ChemComm Blog, 28 Feb 2011 [DOI]

  12. K. Fuchsberger, A. Le Goff, L. Gambazzi, F. M. Toma, A. Goldoni, M. Giugliano, M. Stelzle, M. Prato, “Multi-walled carbon nanotube-functionalized microelectrode arrays fabricated by micro-contact printing: platform for studying chemical and electrical neuronal signaling”, Small 2011, 7 (4), pp 524-530 [DOI]

  13. P. Singh, C. Samorì, F. M. Toma, C. Bussy, A. Nunes, K. T. Al-Jamal, C. Ménard-Moyon, M. Prato, K. Kostarelos, A. Bianco, “Polyamine functionalized carbon nanotubes: synthesis, characterization, cytotoxicity and siRNA binding”, J. Mat. Chem. 2011, 21 (13), pp 4850-4860 [DOI]

  14. P. Singh, F. M. Toma, J. Kumar, V. Venkatesh, M. Prato, J. Raya, S. Verma, A. Bianco, “Carbon nanotubes-nucleobase hybrids: nanorings from uracil-modified single-walled carbon nanotubes”, Chem-Eur. J. 2011, 17 (24), pp 6772-6780 [DOI]

  15. F. M. Toma, A. Sartorel, M. Carraro, M. Bonchio, M. Prato, “Dendron-functionalized multi walled carbon nanotubes incorporating polyoxometalates for water splitting catalysis”, Pure Appl. Chem. 2011, 83 (8), pp 1529-1542 [DOI]

  16. M. Carraro, A. Sartorel, F. M. Toma, F. Puntoriero, F. Scandola, S. Campagna, M. Prato, M. Bonchio “Artificial photosynthesis challenges: water oxidation at nanostructured interfaces”, Top. Curr. Chem. 2011, 303, pp 121-150 [DOI]

  17. F. M. Toma, A. Sartorel, M. Iurlo, M. Carraro, S. Rapino, L. Hoober-Burkhardt, T. Da Ros, M. Marcaccio, G. Scorrano, F. Paolucci, M. Bonchio, M. Prato, “Tailored functionalization of carbon nanotubes for electrocatalytic water splitting and sustainable energy applications”, ChemSusChem 2011, 4 (10), pp 1447-1451 [DOI]

  18. G. Cellot, F. M. Toma, Z. Kasap Varley, J. Laishram, A. Villari, M. Quintana, S. Cipollone, M. Prato, L. Ballerini, “Carbon nanotube scaffolds tune synaptic strength in cultured neural circuits: novel frontiers in nanomaterial-tissue interactions”, J. Neurosci. 2011, 31 (36), pp 12945-12953 [DOI]

  19. P. Singh, G. Lamanna, C. Ménard-Moyon, F. M. Toma, E. Magnano, F. Bondino, M. Prato, S. Verma, A. Bianco, “Formation of efficient catalytic silver nanoparticles on carbon nanotubes by adenine functionalization”, Angew. Chem. Int. Ed. 2011, 59 (42), pp 9893-9897 [DOI]

  20. A. Sartorel, M. Carraro, F. M. Toma, M. Prato, M. Bonchio, “Shaping the beating heart of artificial photosynthesis: oxygenic metal oxide nano-clusters”, En. Env. Science 2012, 5 (2), pp 5592-5603. Inside front cover [DOI]

  21. A. Fabbro, A. Villari, J. Laishram, D. Scaini, F. M. Toma, A. Turco, M. Prato, L. Ballerini, “Spinal cord explants use carbon nanotube interfaces to enhance neurite outgrowth and fortify synaptic inputs”, ACSNano 2012, 6 (3), 2041-2055 [DOI]

  22. V. Martinelli, G. Cellot, F. M. Toma, C. Long, J. Caldwell, L. Zentilin, M. Giacca, A. Turco, M. Prato, L. Ballerini, L. Mestroni, “Carbon nanotubes promote growth and spontaneous electrical activity”, NanoLett. 2012, 12 (4), 1831-1838 [DOI]

  23. L. Maggini,‡ F. M. Toma,‡ L. Feruglio, J. M. Malicka, T. Da Ros, N. Armaroli, M. Prato, D. Bonifazi, “Luminescent blooming of dendronic carbon nanotubes through ion-pairing interactions with an Eu(III) complex”, Chem-Eur. J. 2012, 18 (19), 5889-5897. ‡These authors contributed equally. Cover page, accepted as VIP article and highlighted by Angewandte Spotlights (Angew. Chem. Int. Ed., 2012, 51, 4514 – 4516) [DOI]

  24. K. T. Al-Jamal, A. Nunes, L. Methven, H. Ali-Boucetta, S. Li, F. M. Toma, M. A. Herrero, W. T. Al-Jamal, H. M. M. ten Eikelder, J. Foster, S. Mather, M. Prato, K. Kostarelos, A. Bianco, “Degree of Chemical Functionalization of Carbon Nanotubes Determines Tissue Distribution and Excretion Profile”, Angew. Chem. Int. Ed. 2012, 51 (26), 6389-6393 [DOI]

  25. J. Lee, S. Mubeen, G. Hernandez-Sosa, Y. Sun, F. M. Toma, G. D. Stucky, M. Moskovits, “High Efficiency Panchromatic Hybrid Schottky Solar Cells”, Adv. Mater. 2013, 25 (2), 256–260 [DOI]

  26. T. V. Pho, F. M. Toma, M. L. Chabinyc, F. Wudl, “Self-assembling decacyclene triimides prepared via a regioselective hextuple Friedel-Crafts carbamylation”, Angew. Chem. Int. Ed. 2013, 52 (5), 1446-1451 [DOI]

  27. M. Quintana, A. Montellano López, S. Rapino, F. M. Toma, M. Iurlo, M. Carraro, A. Sartorel, C. Maccato, X. Ke, C. Bittencourt, T. Da Ros, G. Van Tendeloo, M. Marcaccio, F. Paolucci, M. Prato, M. Bonchio, “Energy materials by molecular design: knitting the catalytic pattern of artificial photosynthesis to a hybrid graphene nano-texture”, ACS Nano 2013, 7 (1), 811-817 [DOI]

  28. P. Singh, C. Ménard-Moyon, A. Battigelli, F. M. Toma, J. Kumar, N. Nagapradeep, S. Verma, A. Bianco, “Double Functionalization of Carbon Nanotubes with Purine and Pyrimidine Derivatives”, Chem-Asian J. 2013, 8, 1472-1481 [DOI]

  29. V. Martinelli, G. Cellot, F. M. Toma, C. S. Long, J. H. Caldwell, L. Zentilin, M. Giacca, A. Turco, M. Prato, L. Ballerini, and L. Mestroni, “Carbon nanotubes instruct physiological growth and functionally mature syncytia: non-genetic engineering of neonatal cardiac myocytes”, ACS Nano 2013, 7 (7), 5746-5756. [DOI]

  30. A. Fabbro, A. Sucapane, F. M. Toma, E. Calura, L. Rizzetto, C. Carrieri, P. Roncaglia, V. Martinelli, D. Scaini, L. Masten, A. Turco, S. Gustincich, M. Prato, L. Ballerini, “Adhesion to carbon nanotube conductive scaffolds forces action-potential appearance in immature rat spinal neurons”, PLOS One 2013, 9 (8), e73621 1-14. [DOI]

  31. A. Aldinucci, A. Turco, T. Biagioli, F. M. Toma, D. Bani, D. Guasti, L. Rizzetto, D. Cavalieri, C. Manuelli, L. Massacesi, A. Bianco, L. Ballerini, M. Prato, C. Ballerini, “Carbon nanotube scaffolds instruct human dendritic cells: modulating immune responses by contacts at the nanoscale”, NanoLett. 2013, 12(13), 6098-6105 [DOI]

  32. T. V. Pho, F. M. Toma, B. J. Tremolet de Villers, S. Wang, N. D. Treat, N. Eisenmenger, R. C. Coffin, J. D. Douglas, J. M. J. Fréchet, G. C. Bazan, F. Wudl, M. L. Chabinyc, “Decacyclene Triimides: Paving the Road to Universal Non-Fullerene Acceptors for Organic Photovoltaics”, Adv. Energy. Mater. 2014, 4(5), 1301007 [DOI]

  33. J. Yang, K. Walczak, E. Anzenberg, F. M. Toma, G. Yuan, J. Beeman, A. Schwartzberg, Y. Lin, M. Hettick, A. Javey, J. W. Ager, J. Yano, H. Frei, I. D. Sharp, “Efficient and Sustained Photoelectrochemical Water Oxidation by Cobalt Oxide/Silicon Photoanodes with Nanotextured Interfaces”, J. Am. Chem. Soc. 2014, 136(17), 6191-6194 [DOI]

  34. J. K. Cooper, S. GuI, F. M. Toma, L. Chen, P.-A. Glans, J. Guo, J. W. Ager, I. D. Sharp, “Electronic Structure of Monoclinic BiVO4”, Chem. Mater. 2014, 26(18), 5365-5373 [DOI]

  35. S.-L. Cai, Y.-B. Zhang, A. B. Pun, B. He, J. Yang, F. M. Toma, I. D. Sharp, O. M. Yaghi, J. Fan, S.-R. Zheng, W.-G. Zhang, Y. Liu, “Tunable electrical conductivity in oriented thin films of tetrathiafulvalene-based covalent organic framework”, Chem. Sci. 2014, 5, 4693-4700 [DOI]

  36. Y. Li, J. K. Copper, R. Buonsanti, Cinzia Giannini, Y. Liu, F. M. Toma,* I. D. Sharp,* “Fabrication of Planar Heterojunction Perovskite Solar Cells by Controlled Low-Pressure Vapor Annealing”, J. Phys. Chem. Lett. 2015, 6(3), 493-499 [DOI]

  37. Jason K. Cooper, Sheraz GuI, F. M. Toma, L. Chen, P.-A. Glans, J. Guo, J. W. Ager, I. D. Sharp, “Indirect Bandgap and Optical Properties of Monoclinic Bismuth Vanadate”, J. Phys. Chem. C 2015, 119(6), 2969-2974 [DOI]

  38. L. Chen, F. M. Toma, J. K. Cooper, A. Lyon, Y. Lin, I. D. Sharp, J. W. Ager, “Mo-Doped BiVO4 Photoanodes Synthesized by Reactive Sputtering”, ChemSusChem 2015, 8, 1066-1071 [DOI]

  39. F. M. Toma,‡ F. Puntoriero, T. V. Pho, M. La Rosa, Y.-S. Jun, B. J. Tremolet de Villers, J. Pavlovich, G. D. Stucky, S. Campagna, F. Wudl, “Polyimide Dendrimers Containing Multiple Electron Donor-Acceptor Units and their Unique Photophysical Properties”, Angew. Chem. Int. Ed. 2015, 54 (23), 6775-6779 [DOI]

  40. L. Chen, J. Yang, S. Klaus, L. Lee, R. Woods-Robinson, J. Ma, J. Cooper, F. M. Toma, L.-W. Wang, I. D. Sharp, A. T. Bell, J. W. Ager, “P-type Transparent Conducting Oxide / n-type Semiconductor Heterojunctions for Efficient and Stable Solar Water Oxidation”, J. Am. Chem. Soc. 2015, 137 (30), 9595-9603 [DOI]

  41. C. Guo, W. T. Al-Jamal, F. M. Toma, A. Bianco, M. Prato, K. T. Al-Jamal, K. Kostarelos, “Design of Cationic Multiwalled Carbon Nanotubes as Efficient siRNA Vectors for Lung Cancer Xenograft Eradication”, Bioconjugate Chem. 2015, 26 (7), 1370–1379 [DOI]

  42. D. G. de Oteyza,* J. M. Garcia-Lastra, F. M. Toma,* P. Borghetti, L. Floreano, A. Verdini, A. Cossaro, T. V. Pho, F. Wudl, J. E. Ortega, “Decacyclene-tri-anhydride (DTA) at Functional Interfaces: An Ideal Electron Acceptor Material for Organic Electronics”, J. Phys. Chem. Lett. 2016, 7, pp 90–95 [DOI]

  43. M. M. Ristova, C. Francis, F. M. Toma, K. M. Yu, W. Walukiewicz, “Electrochemical Modification of the Optical and Electrical Properties of Cd-rich NixCd1-xO alloys”, Sol. Ener. Mat. Sol. C. 2016, 147, 127-133 [DOI]

  44. D. Guevarra, A. Shinde, S. K. Suram, I. D. Sharp, F. M. Toma,* J. A. Haber,* J. M. Gregoire,* “Development of solar fuels photoanodes through combinatorial integration of Ni-La-Co-Ce oxide catalysts on BiVO4”, Energy Environ. Sci. 2016, 9, pp 565-580 [DOI]

  45. C. M. Sutter-Fella, Y. Li, M. Amani, J. W. Ager III, F. M. Toma, E. Yablonovitch, I. D. Sharp, A. Javey, “High Photoluminescence Quantum Yield in Band Gap Tunable Bromide Containing Mixed Halide Perovskites”, Nanolett. 2016, 16 (1), pp 800-806 [DOI]

  46. G. D. Nguyen,‡ F. M. Toma,‡ Ting Cao,‡ Z. Pedramrazi, C. Chen, D. J. Rizzo, T. Joshi, C. Bronner, Y.-C. Chen, S. G. Louie, F. R. Fischer, M. F. Crommie, “Bottom-up Synthesis of N=13 Sulfur-doped Graphene Nanoribbons”, J. Phys. Chem. C 2016, 120 (5), pp 2684-2687. ‡These authors contributed equally [DOI]

  47. S. Y. Leblebici, L. Leppert, Y. Li, S. E. Reyes-Lillo, S. Wickenburg, E. Wong, J. Lee, M. Melli, D. Ziegler, D. K. Angell, D. F. Ogletree, P. D. Ashby, F. M. Toma, J. B. Neaton, I. D. Sharp, A. Weber-Bargioni, “Facet-dependent photovoltaic efficiency variations in single perovskite grains”, Nat. Energy 2016, 1, article number: 16093 News Release [DOI]

  48. F. M. Toma,*,‡ J. K. Cooper, V. Kunzelmann, M. T. McDowell, Jie Yu, D. M. Larson N. J. Borys, C. Abelyan, J. W. Beeman, K. M. Yu, J. Yang, L. Chen, M. R. Shaner, J. Spurgeon, F. A. Houle, K. A. Persson, I. D. Sharp,* “Mechanistic Insights into Chemical and Photochemical Transformations of Bismuth Vanadate Photoanodes”, Nat. Commun. 2016, 7, article number: 12012 News Release [DOI]

  49. J. K. Cooper, S. Scott, Y. Ling, J. Yang, S. Hao, Y. Li, F. M. Toma, M. Stutzmann, K. V. Lakshmi, Sharp I. D. “The role of hydrogen in defining the n-type character of BiVO4 photoanodes”, Chem. Mater. 2016, 28(16), 5761-5771 [DOI]

  50. Y. Li, J. Cooper, W. Liu, C. Sutter-Fella, M. Amani, A. Javey, J. W. Ager, Y. Liu, F. M. Toma,* I. D. Sharp,* “Defective TiO2 with high photoconductive gain for efficient and stable planar heterojunction perovskite solar cells”, Nat. Commun. 2016, 7, article number: 12446 [DOI]

  51. A. Shinde, D. Guevarra, G. Liu, I. D. Sharp, F. M. Toma,* J. M. Gregoire,* J. A. Haber,* “Discovery of Fe−Ce Oxide/BiVO4 Photoanodes through Combinatorial Exploration of Ni−Fe−Co−Ce Oxide Coatings”, ACS Appl. Mater. Interface. 2016, 8, pp 23696-23705 [DOI]

  52. A. Shinde, G. Li, L. Zhou, D. Guevarra, S. K. Kumar, F. M. Toma, J. A. Haber, Q. Yan, J. B. Neaton, J. M. Gregoire, “The role of the CeO 2 /BiVO 4 interface in optimized Fe-Ce coatings for solar fuels photoanodes”, J. Mater. Chem. A 2016, 4, pp 14356-14363 [DOI]

  53. J. Yang, J. K. Cooper, F. M. Toma, M. Favaro, J. W. Beeman, K. Walczak, C. Wang, C. Zhu, S. Gul, J. Yano, C. Kisielowski, A. Schwartzberg, I. D. Sharp, “A multi-functional biphasic water splitting catalyst tailored for integration with high performance semiconductor photoanodes”, Nature Mater. 2017, 16, pp 335-341 News Release [DOI]

  54. I. D. Sharp, J. K. Cooper, F. M. Toma, R. Buonsanti, “Bismuth Vanadate as a Platform for Accelerating Discovery and Development of Complex Transition Metal Oxide Photoanodes”, ACS Energy Lett. 2017, 2, pp 139-150 [DOI]

  55. M. Favaro, C. Valero-Vidal, J. Eichhorn, F. M. Toma, P. N. Ross, J. Yano, Z. Liu, E. J. Crumlin, “Elucidating the Alkaline Oxygen Evolution Reaction Mechanism on Platinum”, J. Mater. Chem. A 2017, 5, pp 11634-11643 [DOI]

  56. C. M. Sutter-Fella, D. W. Miller, Q. P. Ngo, E. T. Roe, F. M. Toma, I. D. Sharp, M. C. Lonergan, A. Javey, “Band Tailing and Deep Defect States in CH3NH3Pb(I1-xBrx)3 Perovskites as Revealed by Sub-Bandgap Photocurrent”, ACS Energy Lett. 2017, 2 (3), pp 709-715 [DOI]

  57. E. A. Gaulding, G. Liu, C. T. Chen, L. Löbbert, A. Li, G. Segev, J. Eichhorn, S. Aloni, A. M. Schwartzberg, I. D. Sharp, F. M. Toma,* “Fabrication and optical characterization of polystyrene opal templates for the synthesis of scalable, nanoporous (photo)electrocatalytic materials by electrodeposition”, J. Mater. Chem. A 2017, 5, pp 11601-11614. Inside front cover [DOI]

  58. W. S. Drisdell,* L. Leppert, C. M. Sutter-Fella, Y. Liang, Y. Li, Q. P. Ngo, S. Gul, T. Kroll, D. Sokaras, A. Javey, J. Yano, J. B. Neaton, F. M. Toma,* D. Prendergast,* I. D. Sharp,* “Determining atomic-scale structure and composition of organo-lead halide perovskites by combining high-resolution X-ray absorption spectroscopy and first-principles calculations”, ACS Energy Lett. 2017, 2 (5), pp 1183-1189 [DOI]

  59. M. Favaro, J. Yang, S. Nappini, E. Magnano, F. M. Toma, E. J. Crumlin, J. Yano, and I. D. Sharp, “Understanding the oxygen evolution reaction mechanism on CoOx using operando ambient pressure X-ray photoelectron spectroscopy”, J. Am. Chem. Soc. 2017, 139 (26), pp 8960-8970 [DOI]

  60. C. M. Sutter-Fella, Y. Li, N. Cefarin, A. K. Buckley, Q. P. Ngo, A. Javey, I. D. Sharp,* F. M. Toma,* “Low Pressure Vapor-Assisted Solution Process for Tunable Band Gap Pinhole-free Methylammonium Lead Halide Perovskites Films “, J. Vis. Exp. 2017, 127, e55404 [DOI]

  61. G. Segev, C.-M. Jiang, J. K. Cooper, J. Eichhorn, F. M. Toma, I. D. Sharp, “Quantification of the loss mechanisms in emerging water splitting photoanodes through empirical extraction of the spatial charge collection efficiency”, Energy Environ. Sci. 2018, 11, pp 904-913 [DOI]

  62. C.-M. Jiang, G. Segev, L. H. Hess, G. Liu, G. Zaborski, F. M. Toma, J. K. Cooper, I. D. Sharp, “Composition-Dependent Functionality of Copper Vanadate Photoanodes”, ACS Appl. Mater. Interfaces 2018, 10 (13), pp 10627-10633 [DOI]

  63. C. M. Sutter-Fella, Q. P. Ngo, N. Cefarin, K. L. Gardner, N. Tamura, C. V. Stan, W. S. Drisdell, A. Javey, F. M. Toma, I. D. Sharp, “Cation-Dependent Light-Induced Halide Demixing in Hybrid Organic-Inorganic Perovskites”, Nanolett. 2018, 18 (6), pp 3473-3480 [DOI]

  64. J. Eichhorn, C. Kastl, J. K. Cooper, D. Ziegler, A. M. Schwartzberg, I. D. Sharp, F. M. Toma,* “Nanoscale imaging of charge carrier transport limitations in BiVO4 photoanodes”, Nat. Commun. 2018, 9, 2597. Featured in Nature Communications Editors' Highlights, and News Release [DOI]

  65. M. R. Nellist, J. Qiu, F. A. L. Laskowski, F. M. Toma, S. W. Boettcher, “Potential-Sensing Electrochemical AFM Shows CoPi as a Hole Collector and Oxygen Evolution Catalyst on BiVO4 Water-Splitting Photoanodes”, ACS Energy Lett. 2018, 3 (9), pp 2286-2291 [DOI]

  66. L. Zhou, A. Shinde, D. Guevarra, F. M. Toma, H. S. Stein, J. M. Gregoire, J. A. Haber, “Balancing surface passivation and catalysis with integrated BiVO4/(Fe-Ce)Ox photoanodes in pH 9 borate electrolyte”, ACS Appl. Energy Mater. 2018, 1 (10), pp 5766-5771 [DOI]

  67. J. Eichhorn, C. Kastl, A. M. Schwartzberg, I. D. Sharp, F. M. Toma,* “Disentangling the role of surface chemical interactions on interfacial charge transport at BiVO4 photoanodes”, ACS Appl. Mater. Interfaces 2018, 10 (41), pp 35129-35135 [DOI]

  68. G. Liu, J. Eichhorn, C.-M. Jiang, M. C. Scott, L. H. Hess, J. M. Gregoire, J. A. Haber, I. D. Sharp, F. M. Toma,* “Interface engineering for light-driven water oxidation: Unravelling the passivating and catalytic mechanism in BiVO4 overlayers”, Suistainable Energy and Fuels 2019, 3, 127-135 [DOI]

  69. L. Li, J. Yang, H. Ali-Loytty, T.-C. Weng, F. M. Toma, D. Sokaras, I. D. Sharp, A. Nilsson, “Operando observation of chemical transformations of iridium oxide during photoelectrochemical water oxidation”, ACS Appl. Energy Mater. 2019, 2 (2), pp 1371–1379 [DOI]

  70. C. Kastl, R. J. Koch, C. T. Chen, J. Eichhorn, S. Ulstrup, A. Bostwick, C. Jozwiak, T. R. Kuykendall, N. J. Borys, F. M. Toma, S. Aloni, A. Weber-Bargioni, E. Rotenberg, A. M. Schwartzberg, “Effects of defects on band structure and excitons in WS2 revealed by nanoscale photoemission spectroscopy”, ACS Nano 2019, 13 (2), pp 1284–1291 [DOI]

  71. C. T. Chen, J. Pedrini, E. A. Gaulding, C. Kastl, G. Calafiore, S. Dhuey, T. R. Kuykendall, S. Cabrini, F. M. Toma, S. Aloni, A. M. Schwatzberg, “Very high refractive index transition metal dichalcogenide photonic conformal coatings by conversion of ALD metal oxides”, Sci. Rep. 2019, 9, article number: 2768 [DOI]

  72. G. Gurudayal,  J. W. Beeman,  J. Bullock,  H. Wang,  J. Eichhorn,  C. M. Towle,  A. Javey,  F. M. Toma, N. Mathews,  J. W. Ager, “Si photocathode with Ag-supported dendritic Cu catalyst for CO2 reduction”, Energy Environ. Sci. 2019, 12, 1068-1077 [DOI]

  73. C.-M. Jiang, S. E. Reyes-Lillo, Y. Liang, Y.-S. Liu, G. Liu, F. M. Toma, D. Prendergast, I. D. Sharp, J K. Cooper, “Electronic Structure and Performance Bottlenecks of CuFeO2 Photocathodes”, Chem. Mater. 2019, 31 (7), 2524-2543 [DOI]

  74. A. K. Buckley, M. Lee, T. Cheng, R. V. Kazantsev, D. M. Larson, W. A. Goddard, F. D. Toste,* F. M. Toma,* “Electrocatalysis at Organic-Metal Interfaces: Identification of Structure-Reactivity Relationships for CO2 Reduction at Modified Cu Surfaces”, J. Am. Chem. Soc. 2019, 141 (18), 7355-7364 [DOI]

  75. S. Vanka, K. Sun, G. Zeng, T. A. Pham, F. M. Toma, T. Ogitsu, Z. Mi, “Long-Term Stability Studies of a Semiconductor Photoelectrode Protected by Gallium Nitride Nanostructures”, J. Mater. Chem. A 2019, 7 (48), 27612-27619 [DOI]

  76. A. De Riccardis, M. Lee, R. V. Kazantsev, A. J. Garza, G. Zeng, D. M. Larson, E. L. Clark, P. Lobaccaro, P. W. W. Burroughs, E. Bloise, J. W. Ager, A. T. Bell, M. Head-Gordon, G. Mele,* F. M. Toma,* “Heterogenized Pyridine-Substituted Cobalt(II) Phthalocyanine Yields Reduction of CO2 by Tuning the Electron Affinity of the Co Center”, ACS Appl. Mater. Interfaces 2020, 12 (5), 5251-5258 [DOI]

  77. M. Lee, A. De Riccardis, R. V. Kazantsev, J. K. Cooper, A. K. Buckley, P. W. W. Burrough, D. M. Larson, G. Mele, F. M. Toma,* “Aluminum Metal Organic Framework Triggers Carbon Dioxide Reduction Activity”, ACS Appl. Energy Mater. 2020, 3 (2), 1286-1291, [DOI]

  78. K. Jiang, Y. Huang, G. Zeng, F. M. Toma, W. A. Goddard, A. T. Bell, “Effects of Surface Roughness on the Electrochemical Reduction of CO2 over Cu”, ACS Energy Lett. 2020, 5 (4), 12061-1204 [DOI]

  79. S. H. Lee, I. Sullivan, D. M. Larson, G. Liu, F. M. Toma, C. Xiang, W. S. Drisdell, “Correlating Oxidation State and Surface Area to Activity from Operando Studies of Copper CO Electroreduction Catalysts in a Gas-fed Device”, ACS Catal. 2020, 10, 14, 8000–8011 [DOI]

  80. M. Borgwardt, J. Mahl, F. Roth, L. Wenthaus, F. Brauße, M. Blum, K. Schwarzburg, G. Liu, F. M. Toma, O. Gessner, “Photoinduced Charge Carrier Dynamics and Electron Injection Efficiencies in Au Nanoparticle-Sensitized TiO2 Determined With Picosecond Time-Resolved X-Ray Photoelectron Spectroscopy”, J. Phys. Chem. Lett. 2020, 11, 14, 5476–5481 [DOI]

  81. J. Eichhorn, S. E. Reyes-Lillo, S. Roychoudhury, S. Sallis, J. Weis, D. M. Larson, J. K. Cooper, I. D. Sharp, D. Prendergast, F. M. Toma,* “Revealing Nanoscale Chemical Heterogeneities in Polycrystalline Mo-BiVO4 Thin Films“, Small 2020, in press [DOI]

  82. T. A. Kistler, G. Zeng, J. L. Young, L.-C. Weng, C. Aldridge, K. Wyatt, M. A. Steiner, O. Solorzano Jr., F. A. Houle, F. M. Toma, A. Z. Weber, T. G. Deutsch, N. Danilovic, “Emergent Degradation Phenomena Demonstrated on Resilient, Flexible and Scalable Integrated Photoelectrochemical Cells”, Adv. Energy Mater. 2020, 2002706 [DOI]

  83. L. M. Otto, E. A. Gaulding, C. Chen, T. Kuykendall, A. Hammack, F. M. Toma, D. F. Ogletree, S. Aloni, B. J. H. Stadler, A. M Schwartzberg “Methods for tuning plasmonic and photonic optical resonances in high surface area porous electrodes”, Sci. Rep. 2021, 11, 7656 [DOI]

  84. G. Zeng, T. A. Pham, S. Vanka, G. Liu, C. Song, J. K. Cooper, Z. Mi,* T. Ogitsu,* F. M. Toma,* “Photoelectrochemically Self-Improving Si/GaN Photocathode Towards Efficient and Durable H2 Production”, Nat. Mater. 2021, [DOI]

  85. C. Kim, K. M. Cho, K. Park, J. Y. Kim, G.-T. Yun, F. M. Toma, I. Gereige, H.-T. Jung, “Cu/Cu2O Interconnected Porous Aerogel Catalyst for Highly Productive Electrosynthesis of Ethanol from CO2”, Adv. Funct. Mater. 2021, 2102142 [DOI]

  86. J. Eichhorn, C.-M. Jiang, J. K Cooper, I. D. Sharp, F. M. Toma,* “Nanoscale Heterogeneities and Composition–Reactivity Relationships in Copper Vanadate Photoanodes”, ACS Appl. Mater. Interfaces 2021, 13, 20, 23575–23583 [DOI]

  87. G. Liu, M. Lee, S. Kwon, G. Zeng, J. Eichhorn, A. K. Buckley, F. D. Toste, W. A. Goddard III,* F. M. Toma,* “CO2 reduction on pure Cu produces only H2 after subsurface O is depleted: theory and experiment”, Proc. Natl. Acad. Sci. U.S.A. 2021, 118(23), e2012649118, [DOI]

  88. A. K. Buckley, T. Cheng, M. H. Oh, G. M. Su, J. Garrison, S. W. Utan, C. Zhu, F. D. Toste*, W. A. Goddard III*, F. M. Toma,* “Approaching 100% Selectivity at Low Potential on Ag for Electrochemical CO2 Reduction to CO Using a Surface Additive” ACS Catal. 2021, 11, 15, 9034–9042 [DOI]

  89. H. Li, P. Yu, R. Lei, F. Yang, P. Wen, X. Ma, G. Zeng, J. Guo, F. M. Toma, Y. Qiu, S. M. Geyer, X. Wang, T. Cheng, W. S. Drisdell, “Facet-Selective Deposition of Ultrathin Al2O3 on Copper Nanocrystals for Highly Stable CO2 Electroreduction to Ethylene”, Angew. Chem. Int. Ed. 2021, 133 (47), 25042-25047 [DOI]

  90. G. Liu, F. Zheng, J. Li, G. Zeng, Y. Ye, D. M. Larson, J. Yano, E. J. Crumlin, J. W. Ager, L.-w. Wang, F. M. Toma,* “Investigation and mitigation of degradation mechanisms in Cu2O photoelectrodes for CO2 reduction to ethylene”, Nat. Energy 2021, 6, 1124-1132 [DOI]

  91. S. Neppl, J. Mahl, F. Roth, G. Mercurio, G. Zeng, F. M. Toma, N. Huse, P. Feulner, O. Gessner, “Nanoscale Confinement of Photo-Injected Electrons at Hybrid Interfaces”, J. Phys. Chem. Lett. 2021, 12 (49), 11951-11959 [DOI]